Hole in the Ozone, or Hole in the Head?

No prizes for guessing which.

With today's constant drumbeat of global warming alarmism, it's easy to forget that this is by no means the first time the environmentalists have threatened the End of the World.

It's not; in fact, they seem to make a regular habit of it.  While the media does not generally care to revisit the end results of the previous false alarms, it's really an enlightening subject for anyone who actually cares about both the environment and about human civilization.

The "Ozone Hole" was one of the very first environmental "crises" to enthrall the media.  The more formal term "Ozone depletion" described two phenomena which were clearly observable by science: 1) a steady decline of about 4% per decade in the total amount of ozone in the atmosphere and 2) a seasonal, but much larger, reduction in the amount of ozone over the poles.  The slow overall decline didn't get much ink; it was much snappier to bleat about the "Ozone hole" over the poles.

Ozone is a form of oxygen known as O3 which is formed when electric sparks pass through normal oxygen which is called O2.  Electrical energy such as lightning breaks apart O2 molecules and some of them form O3.

O3 blocks the sun's ultraviolet radiation.  With less O3 in the atmosphere, the crisis-mongers claimed, more ultraviolet hitting the earth would increase skin cancers, sunburn frogs to death, and bring about other such intolerable ills.

The scientists soon found that although O3 breaks down naturally to O2 over time, O3 breaks down faster when it comes into contact with compounds containing chlorine and bromine.  O3 is formed at a more-or-less constant rate due to lightning; the faster it breaks down, of course, the less there is in the atmosphere at any given time.  The more chlorine and bromine molecules are floating around the atmosphere, the faster O3 breaks down, so the less O3 you'll find at any given time.

Chlorine and bromine break down O3 and were therefore bad.

The most important sources of these chemicals were chlorofluorocarbon (CFC) compounds, commonly called freons, and of bromofluorocarbon compounds known as halons.  Worries about ozone escalated to the point that the "Montreal Protocol" banning the industrial use of these compounds came into force in 1989; the UN proclaimed "World Ozone Day" in 1994.

Ozone and Carbon Footprint

"Freon," a DuPont trade name for a CFC which was widely used in refrigerators and air conditioners, fell under the ban.

Unlike the "global warming crisis," the "Ozone crisis" wasn't serious enough to suggest that anyone actually give up anything; the treaty permitted substitute refrigerants instead of banning air conditioning outright.  DuPont supported the Montreal protocol to ban Freon.  The fact that their patent on Freon was about to expire and that they patented a new refrigerant just before the Montreal protocol was signed and their new gas just happened to pass the tests laid out in the protocol may or may not have had anything to do with their support.  Every crisis has its profiteers!

It costs several hundred dollars to recharge a car's air conditioning system with the Freon substitute versus $20 with Freon.  The new refrigerant could not be used in older equipment; expensive conversion was required, thereby collecting another brigade of unlikely ban supporters.

DuPont's patented compound not only cost more to make than Freon, it was not as effective as a refrigerant.  Thus, operating a new air conditioner or refrigerator took more energy than the equivalent Freon-based equipment;.  In other words, saving the ozone layer increased carbon footprint.

The ban on no-longer-patented Freon was the only reason for anyone to use the new patented refrigerant.  Both refrigerants are greenhouse gases to about the same degree; the justification for the switch was only to save the ozone layer.  Nobody was worrying much about greenhouse gases way back then.

What Happened?

It now appears that phasing out CFC has led to increased amounts of O3 remaining in the atmosphere.  Thus, the remedy enforced by the treaty had the desired effect of keeping more ozone in the atmosphere - a relatively unusual regulatory success, in that the bureaucratic remedy did in fact help to fix the problem it was supposed to fix.

Now we come to the unexpected effect.  The Montreal Protocol was signed even though it could not be proved that increased ultraviolet radiation would lead to increased cancers; epidemiologists agreed that the linkage was a reasonable assumption but they couldn't prove it.

In other words, costly change was imposed even though it could not be proved that decreased ozone levels would cause any harm at all.  Sound typical of environmental warnings?  Much yelling, screaming, legislation, and cost based on little or no evidence?

It gets better.

An article "As ozone hole heals, Antarctic could heat up" in Science News, July 5, 2008, p 10 says:

Via a complicated cascade of events, a full recovery of the ozone hole over Antarctica in the coming years could significantly boost warming of the atmosphere over the icy continent.

After years of decline, the springtime concentrations of ozone in the atmosphere high over Antarctica have begun to increase - a sign that the ozone hole is recovering.

That's the good news.  Here's the bad news:

In one sense, however, the ozone hole is somewhat beneficial: It has kept Antarctica cooler than it otherwise would have been, ... The lower atmosphere over Antarctica lacks ozone in the springtime and doesn't absorb as much ultraviolet radiation.  Therefore, it is much cooler than normal, ... [emphasis added]

Guess what?  Ultraviolet radiation carries energy, lots of it - that's why it causes sunburn and why solar heaters work.  When ozone in the air absorbs the ultraviolet radiation instead of passing it down to your skin, the air gets warmer and there's less ultraviolet energy available to power solar heaters.

When there's less ozone in the air, the air doesn't absorb as much UV energy; the air stays cooler, solar energy collection systems work better, and whatever frogs might happen to reside at the poles die of sunburn.  That's why Science News called the ozone hole "somewhat beneficial."

What happens to Antarctic ice as increasing amounts of ozone in the air over it absorb more radiation and the air gets warmer?  The ice melts.  Curing the ozone hole melts more ice and increases sea levels!

If Al Gore is seriously worried about rising sea levels, he ought to advocate letting us return to unpatented, cheaper Freon.  We could save money, cut carbon footprint by using less energy running air conditioners, reduce ozone concentrations, make solar energy systems more effective, cool the air over Antarctica, and Save the Planet!

Ozone might be good for frogs who can't afford sunscreen and shades, but it's bad for sea levels and for solar energy.

Shouting slogans is simple and makes activists feel good about themselves.  It's too bad that really Saving the Planet turns out to be so complicated.

Will Offensicht is a staff writer for Scragged.com and an internationally published author by a different name.  Read other Scragged.com articles by Will Offensicht or other articles on Environment.
Reader Comments
Let me see if I can put this all together.

1) Ozone is broken down in the presence of chlorine.

2) CFC-based refrigerants such as R-12 (freon) were determined to be contributing to the breakdown of atmospheric ozone.

3) The use of R-12 refrigerants was banned in 1995 (http://www.epa.gov/ozone/geninfo/sdreport99.html)

4) Atmospheric ozone absorbs UV radiation, converting it to heat. Thus, more ozone results in more conversion of UV radiation to heat.

5) The "alarming" warming trend that environmental activists scream about started in 1995 - "The 11 warmest years in this set have all occurred within the last 13 years."(http://news.bbc.co.uk/2/hi/science/nature/7142694.stm)

I think the conclusion is inevitable:

ENVIRONMENTAL ACTIVISTS ARE RESPONSIBLE FOR GLOBAL WARMING!
August 27, 2008 8:04 PM
But why is it that allowing the UV rays to hit the ice and snow in the Antarctic instead of the ozone doesn't heat up the ice and snow, and have the same effect (melted ice), only more direct?
August 28, 2008 3:37 AM
Simple, Jason: ice and snow are white. They reflect the heat back up and out. (Of course, SOME of it stays, ice isn't a perfect mirror, but not much.) Whereas when the UV has to travel through miles of absorbent ozone, much more of its energy gets absorbed into the atmosphere, thence to the icepack underneath.
August 28, 2008 9:51 AM
Good point, that didn't occur to me.
August 28, 2008 9:53 AM
BBC News says that Arctic ice is at a "tipping point."

http://news.bbc.co.uk/2/hi/science/nature/7585645.stm

Arctic sea ice has shrunk to the second smallest extent since satellite records began, US scientists have revealed.

The National Snow and Ice Data Center (NSIDC) says that the ice-covered area has fallen below its 2005 level, which was the second lowest on record.

Melting has occurred earlier in the year than usual, meaning that the iced area could become even smaller than last September, the lowest recorded.

Researchers say the Arctic is now at a climatic "tipping point".

Maybe it's already too late to switch back to freon. Ozone would appear to be bad after all.
August 28, 2008 10:36 AM
Slightly off topic, but I just thought I'd throw this out there.

There are many ancient ports that are now landlocked. I don't know why the sea receded, but I'd be willing to bet that it was just as devastating to them then as the sea coming back would be to us now. So that means while we should indeed worry about changes in temperature and changes in sea level it does not mean that we are causing it.

http://www.gisdevelopment.net/application/archaeology/site/archs0004a.htm

Greenland is becoming more verdant and arable farm land is getting closer to what it was when it was first settled by the Vikings.

http://www.nytimes.com/2007/10/28/world/europe/28greenland.html?_r=2&pagewanted=1

And between 1315 and 1317 perhaps the worst famine in European history happened due to unusually wet weather and cool temperatures.

http://en.wikipedia.org/wiki/Great_Famine_of_1315-1317

Go ahead and try to reduce pollution, I like clean air as much as the next guy, but don't destroy our economy to the point that we can't deal with the effects that a changing climate may bring. The climate has changed before, often with devastating effects to some and beneficial effects to others. Just in case we're in the former I would like to have the industry and monetary resources to deal with it.


(quick note on the wiki entry, in my study of the Great Famine, and according to my prof at the time, there were only a handful of reports of cannibalism, there were not 'many incidents' reported by chroniclers. In the end, never just trust what you read on wiki, always verify)
August 29, 2008 1:28 AM
A year later, the hard data according to NASA: "the Arctic warming trend seen in recent decades has indeed resulted from human activities: but not, as is widely assumed at present, those leading to carbon dioxide emissions. Rather, Arctic warming has been caused in large part by laws introduced to improve air quality and fight acid rain."

http://www.theregister.co.uk/2009/04/09/arctic_aerosols_goddard_institute/
April 13, 2009 10:24 PM

While I don't agree or disagree with the question of which refrigerants are better or worse for the environment I do take issue with the accuracy other parts of the article. The cost of the new refrigerants R-134a is about the same as freon R-12. If you had your auto's system changed that would be expensive. However I believe there was a grandfathers period for changing over. That wouldn't prevent unscrupulous mechanics from replacing them. Most people choose not to repair home refrigerators or window units anyhow. Most patents except those for drugs expire in seven years R-12 had been around for a very long time so it was unlikely to be still under a patent. However DuPont is not likely to give its competitors its trade secret manufacturing technology. Better insulation and more efficient motors for non auto compressors save energy now. While new compressors are required for R-134a the biggest change is in what the pressure gages read. When choosing a compressible gas that is only a second order consideration in efficiency. In other words better motors and better insulation save more energy than picking a certain refrigerant.

January 5, 2013 11:47 PM

While I don't agree or disagree with the question of which refrigerants are better or worse for the environment I do take issue with the accuracy other parts of the article. The cost of the new refrigerants R-134a is about the same as freon R-12. If you had your auto's system changed that would be expensive. However I believe there was a grandfathers period for changing over. That wouldn't prevent unscrupulous mechanics from replacing them. Most people choose not to repair home refrigerators or window units anyhow. Most patents except those for drugs expire in seven years R-12 had been around for a very long time so it was unlikely to be still under a patent. However DuPont is not likely to give its competitors its trade secret manufacturing technology. Better insulation and more efficient motors for non auto compressors save energy now. While new compressors are required for R-134a the biggest change is in what the pressure gages read. When choosing a compressible gas that is only a second order consideration in efficiency. In other words better motors and better insulation save more energy than picking a certain refrigerant.

January 5, 2013 11:49 PM

@MIT ALUM You make a good point "better motors and better insulation save more energy than picking a certain refrigerant." That said, however, R-134a is known to be less efficient than Freon. All else being equal, a cooler using Freon uses less energy to operate than one using R-134a. THEREFORE, since all energy sources besides nuclear generate carbon, it is an unarguable fact that using R-134a instead of Freon increases energy use and therefore carbon footprint.

There was a grandfather period for changing a car as you say, BUT once you couldn't get Freon any more because they quit making it, you HAD to change, swelter, or throw away the car. Big choice. HUGE hit to consumers and warmer air in the Antarctic all to the greater glory of DuPont.

January 6, 2013 3:34 PM
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